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Enantiospecific synthesis of substituted 1-norbornanesulfonic acids and 1-norbornanesulfenic and sulfonic acid derivatives

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dc.contributor.authorGarcı́a Martı́nez, Antonio
dc.contributor.authorTeso Vilar, Enrique
dc.contributor.authorMoreno Jiménez, Florencio
dc.contributor.authorGarcı́a Amo, María
dc.date.accessioned2023-06-20T17:22:44Z
dc.date.available2023-06-20T17:22:44Z
dc.date.issued2000-05-05
dc.descriptionReceived 23 November 1999; revised 22 March 2000; accepted 24 March 2000
dc.description.abstractNew homochiral 1-norbornanesulfenic and sulfonic acid derivatives 2–7, as well as the sulfonic acids 8, are easily synthesised starting from 2-methylene-1-norbornylthiotriflates 1. This new class of homochiral bridgehead thiosulfonates was prepared by us from naturally occurring (+)-camphor and (−)-fenchone. Nucleophilic substitution at the sulfenyl sulfur atom is the key step for this synthetic strategy
dc.description.departmentSección Deptal. de Química Orgánica (Óptica y Optometría)
dc.description.facultyFac. de Óptica y Optometría
dc.description.refereedTRUE
dc.description.sponsorshipDirección General de Investigación Científica y Técnica (España)
dc.description.statuspub
dc.eprint.idhttps://eprints.ucm.es/id/eprint/71212
dc.identifier.doi10.1016/S0957-4166(00)00122-1
dc.identifier.issn0957-4166
dc.identifier.officialurlhttps://doi.org/10.1016/S0957-4166(00)00122-1
dc.identifier.urihttps://hdl.handle.net/20.500.14352/58169
dc.issue.number8
dc.journal.titleTetrahedron: Asymmetry
dc.language.isoeng
dc.page.final1717
dc.page.initial1709
dc.publisherElsevier science Ltd.
dc.relation.projectIDPB(97-0264)
dc.rights.accessRightsrestricted access
dc.subject.cdu542.9
dc.subject.cdu66.091
dc.subject.keywordsulfonic acids
dc.subject.keywordhomochiral bridgehead thiosulfonates
dc.subject.keywordenantioselective catalysis
dc.subject.ucmQuímica orgánica (Química)
dc.subject.unesco2306 Química Orgánica
dc.titleEnantiospecific synthesis of substituted 1-norbornanesulfonic acids and 1-norbornanesulfenic and sulfonic acid derivatives
dc.typejournal article
dc.volume.number11
dspace.entity.typePublication
relation.isAuthorOfPublication09111c59-3829-4b92-a9d2-ee099b545e9e
relation.isAuthorOfPublication.latestForDiscovery09111c59-3829-4b92-a9d2-ee099b545e9e

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