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Entropy maximization in the free expansion process

dc.contributor.authorFernández Pineda, Cristóbal
dc.contributor.authorVelasco Maíllo, Santiago
dc.date.accessioned2023-06-20T10:38:51Z
dc.date.available2023-06-20T10:38:51Z
dc.date.issued2005-07
dc.description© 2005 IOP Publishing Ltd. SV thanks financial support by Comisión Interministerial de Ciencia y Tecnología (CICYT) of Spain under grants BFM 2002-01225 FEDER and BFM 2003-07106 FEDER, and by Junta de CyL-FSE of Spain under grants SA080/04 and SA092/04.
dc.description.abstractThe entropy maximum principle is applied to obtain the final equilibrium state in the free expansion of a perfect gas. This provides an example where the entropy of an isolated system at equilibrium has an absolute maximum which is not a local maximum.
dc.description.departmentDepto. de Estructura de la Materia, Física Térmica y Electrónica
dc.description.facultyFac. de Ciencias Físicas
dc.description.refereedTRUE
dc.description.sponsorshipComisión Interministerial de Ciencia y Tecnología (CICYT) of Spain
dc.description.sponsorshipJunta de CyL-FSE of Spain
dc.description.statuspub
dc.eprint.idhttps://eprints.ucm.es/id/eprint/23636
dc.identifier.doi10.1088/0143-0807/26/4/N01
dc.identifier.issn0143-0807
dc.identifier.officialurlhttp://dx.doi.org/10.1088/0143-0807/26/4/N01
dc.identifier.relatedurlhttp://iopscience.iop.org/
dc.identifier.urihttps://hdl.handle.net/20.500.14352/50886
dc.issue.number4
dc.journal.titleEuropean Journal of Physics
dc.language.isoeng
dc.page.finalN16
dc.page.initialN13
dc.publisherIOP Publishing Ltd.
dc.relation.projectIDBFM 2002-01225 FEDER
dc.relation.projectIDBFM 2003-07106 FEDER
dc.relation.projectIDSA080/04
dc.relation.projectIDSA092/04
dc.rights.accessRightsrestricted access
dc.subject.cdu536
dc.subject.ucmTermodinámica
dc.subject.unesco2213 Termodinámica
dc.titleEntropy maximization in the free expansion process
dc.typejournal article
dc.volume.number26
dcterms.references[1] Kestin J 1979 A Course in Thermodynamics vol II (New York: Hemisphere) p 2 [2] Callen H B 1985 Thermodynamics and an Introduction to Thermostatistics 2nd edn (New York: Wiley) pp 25–6 [3] Gibbs J W 1961 The Scientific Papers of J W Gibbs. Thermodynamics vol I (New York: Dover) p 57 [4] Tisza L 1966 Generalized Thermodynamics (Cambridge, MA: MIT Press) p 43 [5] For a general mathematical study of these topics see, for example, Marsden J E and Tromba A J 1988 Vector Calculus 3rd edn (New York: Freeman) chapter 4 [6] Haase R 1969 Thermodynamics of Irreversible Processes (Reading, MA: Addison-Wesley) p 50 [7] Münster A 1970 Classical Thermodynamics (London: Wiley-Interscience) pp 56–8 [8] Sanfeld A 1971 Equilibrium, stability and displacements Physical Chemistry. An Advanced Treatise. Vol. I. Thermodynamics ed W Jost (New York: Academic) chapter 2A (see section X, Stability of Chemical Systems) [9] Haase R 1956 Thermodynamik der Mischphasen (Berlin: Springer) p 105 (See, also, [7]) [10] Fernández-Pineda C and Velasco S 2001 Application of thermodynamic extremum principles Am. J. Phys. 69 1160–5 [11] Velasco S and Fernández-Pineda C 2002 A simple example illustrating the application of thermodynamic extremum principles Eur. J. Phys. 23 501–11
dspace.entity.typePublication
relation.isAuthorOfPublicationae625a23-ad7c-4def-ac08-a08f29fbf9c6
relation.isAuthorOfPublication.latestForDiscoveryae625a23-ad7c-4def-ac08-a08f29fbf9c6

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