Person:
Cortijo Montes, Miguel

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First Name
Miguel
Last Name
Cortijo Montes
URI
https://hdl.handle.net/20.500.14352/76131
Affiliation
Universidad Complutense de Madrid
Faculty / Institute
Ciencias Químicas
Department
Química Inorgánica
Area
Química Inorgánica
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Author: González Prieto, Rodrigo × Subject: 547 ×

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    Ferromagnetic Interactions through Hydrogen Bonds in a One‐Dimensional NiII Coordination Polymer
    (European Journal of Inorganic Chemistry, 2013) Cortijo Montes, Miguel; González Prieto, Rodrigo; Herrero Domínguez, Santiago; Jiménez Aparicio, Reyes; Sánchez-Rivera, Paula
    A one-dimensional coordination polymer [Ni(tp)(OH2)4] (1) (tp = –O2CC6H4CO2–; terephthalate) has been synthesized under environmentally friendly conditions. It has been characterized by elemental analysis, infrared spectroscopy, thermogravimetry, single-crystal and powder X-ray diffraction, and magnetic measurements. Compound 1 is a rare example of 1D polymeric NiII dicarboxylate that shows ferromagnetic interactions through hydrogen bonds. The zigzag arrangement of the NiII octahedral units connected by hydrogen bonds distinguishes compound 1 from other [Ni(dicarboxylate)(OH2)4] compounds, in which the interactions are antiferromagnetic.