Ferromagnetic Interactions through Hydrogen Bonds in a One‐Dimensional Ni<sup>II</sup> Coordination Polymer

Cortijo Montes, Miguel; González Prieto, Rodrigo; Herrero Domínguez, Santiago; Jiménez Aparicio, Reyes; Sánchez-Rivera, Paula

Ferromagnetic Interactions through Hydrogen Bonds in a One‐Dimensional Ni<sup>II</sup> Coordination Polymer

Download

3. 2013 EJIC.pdf (768.26 KB)

Publication date

2013

Authors

Cortijo Montes, Miguel

González Prieto, Rodrigo

Herrero Domínguez, Santiago

Jiménez Aparicio, Reyes

Sánchez-Rivera, Paula

Citations

Exportar

URI

https://hdl.handle.net/20.500.14352/93090

Citation

Cortijo, M., González-Prieto, R., Herrero, S., Jiménez-Aparicio, R. and Sánchez-Rivera, P. (2013), Ferromagnetic Interactions through Hydrogen Bonds in a One-Dimensional NiII Coordination Polymer. Eur. J. Inorg. Chem., 2013: 5523-5527. https://doi.org/10.1002/ejic.201300875

Abstract

A one-dimensional coordination polymer [Ni(tp)(OH2)4] (1) (tp = –O2CC6H4CO2–; terephthalate) has been synthesized under environmentally friendly conditions. It has been characterized by elemental analysis, infrared spectroscopy, thermogravimetry, single-crystal and powder X-ray diffraction, and magnetic measurements. Compound 1 is a rare example of 1D polymeric NiII dicarboxylate that shows ferromagnetic interactions through hydrogen bonds. The zigzag arrangement of the NiII octahedral units connected by hydrogen bonds distinguishes compound 1 from other [Ni(dicarboxylate)(OH2)4] compounds, in which the interactions are antiferromagnetic.