Ferromagnetic Interactions through Hydrogen Bonds in a One‐Dimensional Ni<sup>II</sup> Coordination Polymer

dc.contributor.authorCortijo Montes, Miguel
dc.contributor.authorGonzález Prieto, Rodrigo
dc.contributor.authorHerrero Domínguez, Santiago
dc.contributor.authorJiménez Aparicio, Reyes
dc.contributor.authorSánchez-Rivera, Paula
dc.date.accessioned2024-01-15T12:44:55Z
dc.date.available2024-01-15T12:44:55Z
dc.date.issued2013-09-24
dc.description.abstractA one-dimensional coordination polymer [Ni(tp)(OH2)4] (1) (tp = –O2CC6H4CO2–; terephthalate) has been synthesized under environmentally friendly conditions. It has been characterized by elemental analysis, infrared spectroscopy, thermogravimetry, single-crystal and powder X-ray diffraction, and magnetic measurements. Compound 1 is a rare example of 1D polymeric NiII dicarboxylate that shows ferromagnetic interactions through hydrogen bonds. The zigzag arrangement of the NiII octahedral units connected by hydrogen bonds distinguishes compound 1 from other [Ni(dicarboxylate)(OH2)4] compounds, in which the interactions are antiferromagnetic.
dc.description.departmentDepto. de Química Inorgánica
dc.description.facultyFac. de Ciencias Químicas
dc.description.refereedTRUE
dc.description.statuspub
dc.identifier.citationCortijo, M., González-Prieto, R., Herrero, S., Jiménez-Aparicio, R. and Sánchez-Rivera, P. (2013), Ferromagnetic Interactions through Hydrogen Bonds in a One-Dimensional NiII Coordination Polymer. Eur. J. Inorg. Chem., 2013: 5523-5527. https://doi.org/10.1002/ejic.201300875
dc.identifier.doi10.1002/ejic.201300875
dc.identifier.issn1434-1948
dc.identifier.issn1099-0682
dc.identifier.urihttps://hdl.handle.net/20.500.14352/93090
dc.journal.titleEuropean Journal of Inorganic Chemistry
dc.language.isoeng
dc.page.final5527
dc.page.initial5523
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 Internationalen
dc.rights.accessRightsopen access
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/
dc.subject.cdu547
dc.subject.ucmQuímica
dc.subject.unesco2303 Química Inorgánica
dc.titleFerromagnetic Interactions through Hydrogen Bonds in a One‐Dimensional Ni<sup>II</sup> Coordination Polymer
dc.typejournal article
dspace.entity.typePublication
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relation.isAuthorOfPublication.latestForDiscovery132acb8c-4bb3-439a-abd2-60dcda6f71f4
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