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Controlling Vilsmeier-Haack processes in meso-methylBODIPYs: A new way to modulate finely photophysical properties in boron dipyrromethenes

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dc.contributor.authorPalao Utiel, Eduardo
dc.contributor.authorMontalvillo Jiménez, Laura
dc.contributor.authorEsnal Martínez, Ixone
dc.contributor.authorPrieto Montero, Ruth
dc.contributor.authorRodríguez Agarrabeitia, Antonia
dc.contributor.authorGarcía Moreno, Inmaculada
dc.contributor.authorBañuelos Prieto, Jorge
dc.contributor.authorLópez Arbeloa, Íñigo María
dc.contributor.authorMoya Cerero, Santiago de la
dc.contributor.authorOrtiz García, María Josefa
dc.dateReceived 10 November 2016, Revised 16 January 2017, Accepted 16 February 2017, Available online 20 February 2017.
dc.date.accessioned2023-06-17T22:09:48Z
dc.date.available2023-06-17T22:09:48Z
dc.date.issued2017-06
dc.description.abstractIn the herein work we report the fine and selective control of competitive processes when submitting meso-methylBODIPYs to Vilsmeier-Haack reaction conditions. These competitive processes generate BODIPYs with opposed photophysical properties, from highly fluorescent dyes enabling laser emission, to non-fluorescent singlet-oxygen photosensitizers. The synthetic control is exerted on the basis of the structure of the starting BODIPY, as well as the electrophilic character (hard or soft) of the formylating reagent.en
dc.description.departmentSección Deptal. de Química Orgánica (Óptica y Optometría)
dc.description.facultyFac. de Óptica y Optometría
dc.description.refereedTRUE
dc.description.sponsorshipMinisterio de Economía, Comercio y Empresa (España)
dc.description.sponsorshipGobierno Vasco
dc.description.statuspub
dc.eprint.idhttps://eprints.ucm.es/id/eprint/45051
dc.identifier.citationPalao Utiel, E., Montalvillo Jiménez, L., Esnal Martínez, I. et al. «Controlling Vilsmeier-Haack Processes in Meso-methylBODIPYs: A New Way to Modulate Finely Photophysical Properties in Boron Dipyrromethenes». Dyes and Pigments, vol. 141, junio de 2017, pp. 286-98. DOI.org (Crossref), https://doi.org/10.1016/j.dyepig.2017.02.030.
dc.identifier.doi10.1016/j.dyepig.2017.02.030
dc.identifier.issn0143-7208
dc.identifier.officialurlhttps://doi.org/10.1016/j.dyepig.2017.02.030
dc.identifier.relatedurlhttp://www.sciencedirect.com/science/article/pii/S0143720816311652
dc.identifier.urihttps://hdl.handle.net/20.500.14352/18156
dc.journal.titleDyes and Pigments
dc.language.isoeng
dc.page.final298
dc.page.initial286
dc.publisherElsevier
dc.relation.projectIDMAT2014-51937-C3-1-P
dc.relation.projectIDMAT2014-51937-C3-2-P
dc.relation.projectIDMAT2014-51937-C3-3-P
dc.relation.projectIDMAT2015-68837-REDT
dc.relation.projectIDIT912-16
dc.rights.accessRightsrestricted access
dc.subject.cdu547.1
dc.subject.cdu539.2:620.1
dc.subject.keywordVilsmeier-Haack
dc.subject.keywordOrganic synthesis
dc.subject.keywordBODIPY
dc.subject.keywordPhotophysics
dc.subject.keywordLaser dyes
dc.subject.keywordCharge transfer
dc.subject.ucmOptica (Química)
dc.subject.ucmQuímica orgánica (Química)
dc.subject.unesco2306 Química Orgánica
dc.titleControlling Vilsmeier-Haack processes in meso-methylBODIPYs: A new way to modulate finely photophysical properties in boron dipyrromethenesen
dc.typejournal article
dc.volume.number141
dspace.entity.typePublication
relation.isAuthorOfPublication0486160c-3df6-4270-bf91-3e96cd33d85d
relation.isAuthorOfPublication7940c6e8-25c3-4083-b533-0c34e155dfa8
relation.isAuthorOfPublication07f337af-8a30-4929-81db-4e92176e5c87
relation.isAuthorOfPublication.latestForDiscovery07f337af-8a30-4929-81db-4e92176e5c87

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