Platinum and Gold Catalysis: à la Carte Hydroamination of Terminal Activated Allenes with Azoles
| dc.contributor.author | Alonso Gómez, José Miguel | |
| dc.contributor.author | Muñoz, María Paz | |
| dc.date.accessioned | 2024-01-11T10:20:10Z | |
| dc.date.available | 2024-01-11T10:20:10Z | |
| dc.date.issued | 2019 | |
| dc.description.abstract | Nucleophilic additions to allenes catalyzed by transition metals represent a powerful tool to obtain selective access to diverse structures with numerous applications. Reported here is a straightforward methodology to achieve selective addition of azoles to the proximal or distal carbon of activated allenes depending on the catalyst used, unravelling a gold–platinum bimetallic catalysis approach for the 1,3-double addition of azoles to activated allenes to give 1,3-bisazole derivatives, an important scaffold in medicinal and organometallic chemistry. | |
| dc.description.department | Depto. de Química Orgánica | |
| dc.description.faculty | Fac. de Ciencias Químicas | |
| dc.description.refereed | TRUE | |
| dc.description.sponsorship | University of East Anglia (Reino Unido) | |
| dc.description.sponsorship | The Leverhulme Trust (Reino Unido) | |
| dc.description.status | pub | |
| dc.identifier.citation | Alonso, José Miguel, y María Paz Muñoz. «Platinum and Gold Catalysis: À La Carte Hydroamination of Terminal Activated Allenes with Azoles». Organic Letters, vol. 21, n.o 18, septiembre de 2019, pp. 7639-44. https://doi.org/10.1021/acs.orglett.9b02949. | |
| dc.identifier.doi | 10.1021/acs.orglett.9b02949 | |
| dc.identifier.essn | 1523-7052 | |
| dc.identifier.issn | 1523-7060 | |
| dc.identifier.officialurl | https://doi.org/10.1021/acs.orglett.9b02949 | |
| dc.identifier.uri | https://hdl.handle.net/20.500.14352/92460 | |
| dc.issue.number | 18 | |
| dc.journal.title | Organic Letters | |
| dc.language.iso | eng | |
| dc.page.final | 7644 | |
| dc.page.initial | 7639 | |
| dc.publisher | American Chemical Society | |
| dc.rights.accessRights | restricted access | |
| dc.subject.cdu | 547 | |
| dc.subject.ucm | Química orgánica (Química) | |
| dc.subject.unesco | 2306 Química Orgánica | |
| dc.title | Platinum and Gold Catalysis: à la Carte Hydroamination of Terminal Activated Allenes with Azoles | |
| dc.type | journal article | |
| dc.type.hasVersion | VoR | |
| dc.volume.number | 21 | |
| dspace.entity.type | Publication | |
| relation.isAuthorOfPublication | d770fa51-b1e8-4963-9d05-4c3f2fcc4380 | |
| relation.isAuthorOfPublication.latestForDiscovery | d770fa51-b1e8-4963-9d05-4c3f2fcc4380 |
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