Tailoring the Molecular Skeleton of Aza-BODIPYs to Design Photostable Red-Light-Emitting Laser Dyes

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dc.contributor.authorPrieto Castañeda, Alejandro
dc.contributor.authorAvellanal Zaballa, Edurne
dc.contributor.authorGartzia Rivero, Leire
dc.contributor.authorCerdán Pedraza, Luis
dc.contributor.authorRodríguez Agarrabeitia, Antonia
dc.contributor.authorGarcía Moreno, Inmaculada
dc.contributor.authorBañuelos Prieto, Jorge
dc.contributor.authorOrtiz García, María Josefa
dc.date.accessioned2023-06-17T12:31:27Z
dc.date.available2023-06-17T12:31:27Z
dc.date.issued2018-11-28
dc.description.abstractIn this article the design and characterization of a set of novel red‐light‐emitting laser aza‐BODIPY dyes is reported. The applied synthetic method allows an exhaustive and versatile functionalization of both the dipyrrin core and the boron bridge. From the analysis of the photophysical and laser signatures, we determine the suitable modifications of the chromophoric backbone necessary to modulate the emission spectral region, efficiency and photostability under a strong irradiation regime. These dyes are endowed with efficient fluorescence and laser emission, and are particularly outstanding in terms of their high photostability, a key parameter to guarantee long‐lasting emission in any (bio)technological application. The herein‐reported results support, for the first time, the viability of aza‐BODIPYs as tunable red laser dyes. In fact, the laser performances of some of the tested aza‐BODIPYs surpass those of commercially available laser dyes in the same spectral region.
dc.description.departmentSección Deptal. de Química Orgánica (Óptica y Optometría)
dc.description.facultyFac. de Óptica y Optometría
dc.description.refereedTRUE
dc.description.sponsorshipMinisterio de Economía y Competitividad (MINECO)
dc.description.sponsorshipGobierno Vasco
dc.description.sponsorshipConsejería de Educación, Juventud y Deporte de la Comunidad de Madrid (España)
dc.description.statuspub
dc.eprint.idhttps://eprints.ucm.es/id/eprint/62007
dc.identifier.doi10.1002/cptc.201800225
dc.identifier.issn2367-0932
dc.identifier.officialurlhttps://doi.org/10.1002/cptc.201800225
dc.identifier.relatedurlhttps://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/cptc.201800225
dc.identifier.urihttps://hdl.handle.net/20.500.14352/12386
dc.issue.number2
dc.journal.titleChemPhotoChem
dc.language.isoeng
dc.page.final85
dc.page.initial75
dc.publisherWiley-VCH Verlag
dc.relation.projectID(MAT2017‐83856‐C3‐1‐P, 2‐P and 3‐P; MAT2015‐68837‐REDT)
dc.relation.projectIDIT912‐16
dc.relation.projectIDCT2/17/CT3/17/ PEJ16/MED/AI‐1598
dc.rights.accessRightsrestricted access
dc.subject.cdu535.374
dc.subject.cdu543.426
dc.subject.cdu547.1
dc.subject.keywordAza-BODIPY
dc.subject.keywordLaser
dc.subject.keywordRed Light laser
dc.subject.keywordPhotostability
dc.subject.keywordLaser dyes
dc.subject.ucmÓptica (Física)
dc.subject.ucmBioquímica (Química)
dc.subject.ucmLáseres
dc.subject.unesco2209.19 Óptica Física
dc.subject.unesco2209.10 Láseres
dc.titleTailoring the Molecular Skeleton of Aza-BODIPYs to Design Photostable Red-Light-Emitting Laser Dyes
dc.typejournal article
dc.volume.number3
dspace.entity.typePublication
relation.isAuthorOfPublicationbee889c2-938d-48d9-8748-01e3c8bf5614
relation.isAuthorOfPublication0486160c-3df6-4270-bf91-3e96cd33d85d
relation.isAuthorOfPublication07f337af-8a30-4929-81db-4e92176e5c87
relation.isAuthorOfPublication.latestForDiscoverybee889c2-938d-48d9-8748-01e3c8bf5614
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