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Optical spectroscopic study of the SiN/HfO2 interfacial formation during rf sputtering of HfO2

dc.contributor.authorMartil De La Plaza, Ignacio
dc.contributor.authorGonzález Díaz, Germán
dc.contributor.authorPrado Millán, Álvaro Del
dc.contributor.authorSan Andrés Serrano, Enrique
dc.date.accessioned2023-06-20T10:44:04Z
dc.date.available2023-06-20T10:44:04Z
dc.date.issued2007-11-05
dc.description© 2007 American Institute of Physics. This work was partially supported by the Spanish M.E.C. under TEC2004 1237/MIC and TEC2007/63318 contracts.
dc.description.abstractHigh-k stacks formed by chemical-vapor-deposited SiN and high-pressure sputtered HfO2 in either O-2 or Ar atmosphere have been studied. The introduction of a SiN layer is proposed to prevent the uncontrollable SiO2 growth while sputtering. The formation of Si-O bonds after the sputtering of the HfO2 film in O-2 atmosphere was observed by infrared spectroscopy. Optical diagnosis of the plasma demonstrated a high density of O radicals in the system when working with O-2. The small radius and high reactivity of these O radicals are the source of the SiN oxidation. However, the structure of the SiN film is preserved during Ar sputtering.
dc.description.departmentDepto. de Estructura de la Materia, Física Térmica y Electrónica
dc.description.facultyFac. de Ciencias Físicas
dc.description.refereedTRUE
dc.description.sponsorshipSpanish M.E.C.
dc.description.statuspub
dc.eprint.idhttps://eprints.ucm.es/id/eprint/25981
dc.identifier.doi10.1063/1.2811958
dc.identifier.issn0003-6951
dc.identifier.officialurlhttp://dx.doi.org/10.1063/1.2811958
dc.identifier.relatedurlhttp://scitation.aip.org
dc.identifier.urihttps://hdl.handle.net/20.500.14352/51104
dc.issue.number19
dc.journal.titleApplied physics Letters
dc.language.isoeng
dc.publisherAmer Inst Physics
dc.relation.projectIDTEC2004-1237/MI
dc.relation.projectIDTEC2007/63318
dc.rights.accessRightsopen access
dc.subject.cdu537
dc.subject.keywordThin-Films.
dc.subject.ucmElectricidad
dc.subject.ucmElectrónica (Física)
dc.subject.unesco2202.03 Electricidad
dc.titleOptical spectroscopic study of the SiN/HfO2 interfacial formation during rf sputtering of HfO2
dc.typejournal article
dc.volume.number91
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