Aviso: para depositar documentos, por favor, inicia sesión e identifícate con tu cuenta de correo institucional de la UCM con el botón MI CUENTA UCM. No emplees la opción AUTENTICACIÓN CON CONTRASEÑA
 

Test of universal scaling of ac conductivity in ionic conductors

dc.contributor.authorLeón Yebra, Carlos
dc.contributor.authorLunkenheimer, P.
dc.contributor.authorNgai, K. L.
dc.date.accessioned2023-06-20T20:07:49Z
dc.date.available2023-06-20T20:07:49Z
dc.date.issued2001-10-01
dc.description© 2001 The American Physical Society. The work performed at the Naval Research Laboratory was supported by ONR. We thank J. Ullrich for help in the dielectric measurements and J. Santamaría and C. T. Moynihan for helpful discussions.
dc.description.abstractElectrical relaxation data of crystalline yttria-stabilized zirconia are used to analyze the permittivity change observed in the spectra of the real part of the permittivity in ionic conducting materials. It is found that this permittivity change is independent of both temperature and mobile-ion concentration, and it is determined solely by the degree of interaction among ions in the relaxation process. This finding is at odds with an expression for the permittivity change in the framework of a proposed universal ac conductivity scaling law for glassy ionic conductors. On the other hand, not only the total permitivity change, but also the particular frequency dependence of the permittivity spectra is found to be consistent with the analysis of electrical relaxation in terms of the electric modulus. The results of this work give further support to the use of the electric modulus in describing electrical relaxation in ionic conductors.
dc.description.departmentDepto. de Estructura de la Materia, Física Térmica y Electrónica
dc.description.facultyFac. de Ciencias Físicas
dc.description.refereedTRUE
dc.description.sponsorshipONR
dc.description.statuspub
dc.eprint.idhttps://eprints.ucm.es/id/eprint/31102
dc.identifier.doi10.1103/PhysRevB.64.184304
dc.identifier.issn0163-1829
dc.identifier.officialurlhttp://dx.doi.org/10.1103/PhysRevB.64.184304
dc.identifier.relatedurlhttp://journals.aps.org/
dc.identifier.urihttps://hdl.handle.net/20.500.14352/59630
dc.issue.number18
dc.journal.titlePhysical review B
dc.language.isoeng
dc.publisherAmerican Physical Society
dc.rights.accessRightsopen access
dc.subject.cdu537
dc.subject.keywordElectrical-field relaxation
dc.subject.keywordIodide-silver selenate
dc.subject.keywordDielectric-relaxation
dc.subject.keywordActivation-energies
dc.subject.keywordDecay function
dc.subject.keywordSpin-lattice
dc.subject.keywordMobile ions
dc.subject.keywordGlasses
dc.subject.keywordSpectra
dc.subject.keywordDynamics.
dc.subject.ucmElectricidad
dc.subject.ucmElectrónica (Física)
dc.subject.unesco2202.03 Electricidad
dc.titleTest of universal scaling of ac conductivity in ionic conductors
dc.typejournal article
dc.volume.number64
dcterms.references1) P.B. Macedo, C.T. Moynihan, R. Bose, Phys. Chem. Glasses, 13, 171 (1972). 2) V. Provenzano, L.P. Boesch, V. Volterra, C.T. Moynihan, P.B. Macedo, J. Am. Ceram. Soc., 55, 492 (1972). 3) C.T. Moynihan, L.P. Boesch, N.L. Laberge, Phys. Chem. Glasses, 14, 122 (1973). 4) F.S. Howell, R.A. Bose, P.B. Macedo, C.T. Moynihan, J. Phys. Chem., 78, 639 (1974). 5) A.K. Jonscher, Dielectric Relaxation in Solids (Chelsea Dielectric Press, London, 1983). 6) C.A. Angell, Chem. Rev., 90, 523 (1990). 7) J.H. Simmons, P.B. Elterman, C.J. Simmons, R.K. Mohr, J. Am. Ceram. Soc., 62, 158 (1979). 8) J.F. Cordaro, M. Tomozawa, J. Am. Ceram. Soc., 64, 713 (19819. 9) K.L. Ngai, R.W. Rendell, H. Jain, Phys. Rev. B, 30, 2133 (1984). 10) H.K. Patel, S.W. Martin, Phys. Rev. B, 45, 10 292 (1992). 11) C. Cramer, K. Funke, T. Saatkamp, Philos. Mag. B, 71, 701 (1995). 12) D.L. Sidebottom, P.F. Green, R.K. Brow, Phys. Rev. B, 56, 170 (1997). 13) C. León, J. Santamaría, M.A. París, J. Sanz, J. Ibarra, L.M. Torres, Phys. Rev. B, 56, 5302 (1997). 14) P. Lunkenheimer, A. Pimenov, A. Loidl, Phys. Rev. Lett., 78, 2995 (1997). 15) C. León, M.L. Lucía, J. Santamaría, Phys. Rev. B, 55, 882 (1997). 16) A. Pimenov, J. Ullrich, P. Lunkenheimer, A. Loidl, C.H. Rüscher, Solid State Ionics, 109, 111 (1998). 17) C. Cramer, M. Buscher, Solid State Ionics, 105, 109 (1998). 18) K.L. Ngai, J. Non-Cryst. Solids, 248, 194 (1999). 19) K.L. Ngai, C.T. Moynihan, MRS Bull., 23, 11, 51 (1998). 20) H. Jain, S. Krishnaswami, Solid State Ionics, 105, 129 (1998). 21) B. Roling, A. Happe, K. Funke, M.D. Ingram, Phys. Rev. Lett., 78, 2160 (1997). 22) B. Roling, Solid State Ionics, 105, 185 (1998). 23) D.L. Sidebottom, Phys. Rev. Lett., 82, 3653 (1999). 24) K.L. Ngai, R.W. Rendell, Phys. Rev. B, 61, 9393 (2000). 25) K.L. Ngai, Phys. Rev. B, 48, 13, 481 (1993) --- J. Chem. Phys., 98, 6424 (1993). 26) K.L. Ngai, G.N. Greaves, C.T. Moynihan, Phys. Rev. Lett., 80, 1018 (1998). 27) K.L. Ngai, C. León, Phys. Rev. B, 60, 9396 (1999). 28) H. Wagner, R. Richter, J. Appl. Phys., 85, 1750 (1999). 29) R. Kohlrausch, Ann. Phys. (Leipzig), 72, 393 (1847) --- G. Williams, D.C. Watts, Trans. Faraday Soc., 66, 80 (1970). 30) K.L. Ngai, U. Strom, Phys. Rev. B, 38, 10, 350 (1988). 31) B. Munro, M. Schrader, P. Heitjans, Ber. Bunsunger, Ber. Bunsenges, Phys. Chem., 96, 1718 (1992) --- W. Franke, P. Heitjans, ibid., 96, 1674 (1992).
dspace.entity.typePublication
relation.isAuthorOfPublication213f0e33-39f1-4f27-a134-440d5d16a07c
relation.isAuthorOfPublication.latestForDiscovery213f0e33-39f1-4f27-a134-440d5d16a07c

Download

Original bundle

Now showing 1 - 1 of 1
Loading...
Thumbnail Image
Name:
LeonC94libre.pdf
Size:
76.22 KB
Format:
Adobe Portable Document Format

Collections