Negishi reaction in BODIPY dyes. Unprecedented alkylation by palladium-catalyzed C–C coupling in boron dipyrromethene derivatives

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dc.contributor.authorDurán Sampedro, Gonzalo
dc.contributor.authorPalao, Eduardo
dc.contributor.authorRodríguez Agarrabeitia, Antonia
dc.contributor.authorMoya Cerero, Santiago de la
dc.contributor.authorBoens, Noël
dc.contributor.authorOrtiz García, María Josefa
dc.date.accessioned2024-02-05T12:07:14Z
dc.date.available2024-02-05T12:07:14Z
dc.date.issued2014
dc.description.abstractNegishi reactions of 3-halogen and 3,5-dihalogen substituted BODIPYs with different organozinc reagents are reported as the first examples of this valuable palladium-catalyzed C–C coupling reaction into the family of the BODIPY dyes. It is demonstrated that the Negishi coupling is especially useful for obtaining interesting alkylated BODIPYs, including synthetically-valuable asymmetrically-3,5-disubstituted BODIPYs.en
dc.description.departmentDepto. de Química Orgánica
dc.description.facultyFac. de Ciencias Químicas
dc.description.refereedTRUE
dc.description.sponsorshipMinisterio de Economía, Comercio y Empresa (España)
dc.description.statuspub
dc.identifier.citationDurán Sampedro, G., Palao, E., Rodríguez Agarrabeitia, A. et al. «Negishi Reaction in BODIPY Dyes. Unprecedented Alkylation by Palladium-Catalyzed C–C Coupling in Boron Dipyrromethene Derivatives». RSC Adv., vol. 4, n.o 37, 2014, pp. 19210-13. https://doi.org/10.1039/C4RA00651H.
dc.identifier.doi10.1039/c4ra00651h
dc.identifier.issn2046-2069
dc.identifier.officialurlhttps://doi.org/10.1039/c4ra00651h
dc.identifier.relatedurlhttps://pubs.rsc.org/en/content/articlelanding/2014/ra/c4ra00651h
dc.identifier.urihttps://hdl.handle.net/20.500.14352/98895
dc.issue.number37
dc.journal.titleRSC Advances
dc.language.isoeng
dc.page.final19213
dc.page.initial19210
dc.publisherRoyal Society of Chemistry
dc.relation.projectIDinfo:eu-repo/grantAgreement/MICINN//MAT2010-20646-C04-02/ES/DISEÑO, SINTESIS Y CARACTERIZACION DE NUEVOS COLORANTES ORGANICOS CON EMISION EN LA REGION ESPECTRAL DEL AZUL, ROJO E IR CERCANO, PARA APLICACIONES AVANZADAS/
dc.rights.accessRightsrestricted access
dc.subject.cdu547
dc.subject.keywordPhotophysycal properties
dc.subject.keywordEnergy-transfer
dc.subject.keywordFluorescence
dc.subject.ucmQuímica orgánica (Química)
dc.subject.unesco22 Física
dc.subject.unesco23 Química
dc.subject.unesco33 Ciencias Tecnológicas
dc.titleNegishi reaction in BODIPY dyes. Unprecedented alkylation by palladium-catalyzed C–C coupling in boron dipyrromethene derivativesen
dc.typejournal article
dc.type.hasVersionVoR
dc.volume.number4
dspace.entity.typePublication
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relation.isAuthorOfPublication0486160c-3df6-4270-bf91-3e96cd33d85d
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relation.isAuthorOfPublication.latestForDiscovery7940c6e8-25c3-4083-b533-0c34e155dfa8

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