Publication:
Phase-Selective Microwave Assisted Synthesis of Iron(III) Aminoterephthalate MOFs

dc.contributor.authorArenas-Vivo, Ana
dc.contributor.authorÁvila Brande, David
dc.contributor.authorHorcajada, Patricia
dc.date.accessioned2023-06-17T09:08:33Z
dc.date.available2023-06-17T09:08:33Z
dc.date.issued2020-03-23
dc.description.abstractIron(III) aminoterephthalate Metal-Organic Frameworks (Fe-BDC-NH2 MOFs) have been demonstrated to show potential for relevant industrial and societal applications (i.e., catalysis, drug delivery, gas sorption). Nevertheless, further analysis is required in order to achieve their commercial production. In this work, a systematic synthetic strategy has been followed, carrying out microwave (MW) assisted hydro/solvothermal reactions to rapidly evaluate the influence of different reaction parameters (e.g., time, temperature, concentration, reaction media) on the formation of the benchmarked MIL-101-NH2, MIL-88B-NH2, MIL-53-NH2 and MIL-68-NH2 solids. Characterization of the obtained solids by powder X-ray diffraction, dynamic light scattering and transmission electron microscopy allowed us to identify trends to the contribution of the evaluated parameters, such as the relevance of the concentration of precursors and the impact of the reaction medium on phase crystallization. Furthermore, we presented here for the first time the MW assisted synthesis of MIL-53-NH2 in water. In addition, pure MIL-101-NH2 was also produced in water while MIL-88-NH2 was the predominant phase obtained in ethanol. Pure phases were produced with high space-time yields, unveiling the potential of MW synthesis for MOF industrialization.
dc.description.departmentDepto. de Química Inorgánica
dc.description.facultyFac. de Ciencias Químicas
dc.description.refereedTRUE
dc.description.sponsorshipMinisterio de Economía y Competitividad (MINECO)/FEDER
dc.description.sponsorshipMinisterio de Economía y Competitividad (MINECO)
dc.description.sponsorshipFundación Ramón Areces
dc.description.sponsorshipPrograma Ramón y Cajal
dc.description.statuspub
dc.eprint.idhttps://eprints.ucm.es/id/eprint/66537
dc.identifier.doi10.3390/ma13061469
dc.identifier.issn1996-1944
dc.identifier.officialurlhttps://doi.org/10.3390/ma13061469
dc.identifier.relatedurlhttps://www.mdpi.com/1996-1944/13/6/1469
dc.identifier.urihttps://hdl.handle.net/20.500.14352/8263
dc.issue.number6
dc.journal.titleMaterials
dc.language.isoeng
dc.page.initial1469
dc.publisherMDPI
dc.relation.projectIDENE2016-79608-C2-1-R
dc.relation.projectIDMAT2017-84385-R
dc.relation.projectIDH+MOFs
dc.relation.projectID2014-15039
dc.rightsAtribución 3.0 España
dc.rights.accessRightsopen access
dc.rights.urihttps://creativecommons.org/licenses/by/3.0/es/
dc.subject.keywordmicrowave synthesis
dc.subject.keywordmetal-organic frameworks
dc.subject.keywordporous solids
dc.subject.keywordiron
dc.subject.keywordaminoterphthalate
dc.subject.keywordphase selection
dc.subject.ucmMetalurgia
dc.subject.ucmQuímica inorgánica (Química)
dc.subject.unesco2211.21 Metalurgia
dc.subject.unesco2303 Química Inorgánica
dc.titlePhase-Selective Microwave Assisted Synthesis of Iron(III) Aminoterephthalate MOFs
dc.typejournal article
dc.volume.number13
dspace.entity.typePublication
relation.isAuthorOfPublicationb9cc815b-035a-4792-9340-812f5a77dd77
relation.isAuthorOfPublication.latestForDiscoveryb9cc815b-035a-4792-9340-812f5a77dd77
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