Lithium Storage Mechanisms and Effect of Partial Cobalt Substitution in Manganese Carbonate Electrodes

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dc.contributor.authorMirhashemihaghighi, Shadi
dc.contributor.authorLeón, Bernardo
dc.contributor.authorPérez Vicente, Carlos
dc.contributor.authorTirado Fernández, José Francisco
dc.contributor.authorStoyanova, Radostina
dc.contributor.authorYoncheva, Meglena
dc.contributor.authorZhecheva, Ekaterina
dc.contributor.authorSáez Puche, Regino
dc.contributor.authorArroyo De Dompablo, María Elena
dc.contributor.authorRomero de Paz, Julio
dc.date.accessioned2024-02-05T08:13:57Z
dc.date.available2024-02-05T08:13:57Z
dc.date.issued2012
dc.description.abstractA promising group of inorganic salts recently emerged for the negative electrode of advanced lithium-ion batteries. Manganese carbonate combines low weight and significant lithium storage properties. Electron paramagnetic resonance (EPR) and magnetic measurements are used to study the environment of manganese ions during cycling in lithium test cells. To observe reversible lithium storage into manganese carbonate, preparation by a reverse micelles method is used. The resulting nanostructuration favors a capacitive lithium storage mechanism in manganese carbonate with good rate performance. Partial substitution of cobalt by manganese improves cycling efficiency at high rates.
dc.description.departmentDepto. de Química Inorgánica
dc.description.facultyFac. de Ciencias Químicas
dc.description.refereedTRUE
dc.description.statuspub
dc.identifier.citationShadi Mirhashemihaghighi, Bernardo León, Carlos Pérez Vicente, José L. Tirado, Radostina Stoyanova, Meglena Yoncheva, Ekaterina Zhecheva, Regino Sáez Puche, Elena M. Arroyo, and Julio Romero de Paz Inorganic Chemistry 2012 51 (10), 5554-5560 DOI: 10.1021/ic3004382
dc.identifier.doi10.1021/ic3004382
dc.identifier.issn0020-1669
dc.identifier.officialurlhttps://doi.org/10.1021/ic3004382
dc.identifier.urihttps://hdl.handle.net/20.500.14352/98619
dc.journal.titleInorganic Chemistry
dc.language.isoeng
dc.page.final5560
dc.page.initial5554
dc.publisherAmerican Chemical Society
dc.relation.projectIDinfo:eu-repo/grantAgreement/MICINN//MAT2008-05880/ES/OXISALES PARA LOS ELECTRODOS DE INSERCION%2FCONVERSION DE BATERIAS AVANZADAS DE ION LITIO E ION SODIO/
dc.relation.projectIDinfo:eu-repo/grantAgreement/MICINN//MAT2011-22753/ES/HACIA UNA BATERIA ION-LI DE ESTADO SOLIDO: MATERIALES NANOESTRUCTURADOS OBTENIDOS POR VIA ELECTROQUIMICA/
dc.rightsAttribution 4.0 Internationalen
dc.rights.accessRightsrestricted access
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/
dc.subject.cdu546
dc.subject.ucmQuímica inorgánica (Química)
dc.subject.ucmFísica de materiales
dc.subject.unesco2303.29 Elementos de Transición
dc.titleLithium Storage Mechanisms and Effect of Partial Cobalt Substitution in Manganese Carbonate Electrodes
dc.typejournal article
dc.type.hasVersionVoR
dc.volume.number51
dspace.entity.typePublication
relation.isAuthorOfPublication1356616c-9e69-4852-8415-62fd0b8e7cfc
relation.isAuthorOfPublicationb28d866e-85f4-4a0e-a91b-dc263c1aaa45
relation.isAuthorOfPublication7111ee3d-1efb-48ae-8e55-b5d1275a99da
relation.isAuthorOfPublication.latestForDiscoveryb28d866e-85f4-4a0e-a91b-dc263c1aaa45
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