Synthesis and functionalization of new polyhalogenated BODIPY dyes. Study of their photophysical properties and singlet oxygen generation
Loading...
Official URL
Full text at PDC
Publication date
2012
Advisors (or tutors)
Editors
Journal Title
Journal ISSN
Volume Title
Publisher
Elsevier Ltd.
Citation
Ortiz García, M. J., Rodríguez Agarrabeitia, A., Durán Sampedro, G. et al. «Synthesis and Functionalization of New Polyhalogenated BODIPY Dyes. Study of Their Photophysical Properties and Singlet Oxygen Generation». Tetrahedron, vol. 68, n.o 4, enero de 2012, pp. 1153-62. https://doi.org/10.1016/j.tet.2011.11.070.
Abstract
A theoretical and experimental study on the iodination of BODIPY dyes with different degrees of substitution has been developed. Polyhalogenated BODIPYs synthesized in this work are the first examples of this type of dyes with more than two halogen atoms in the BODIPY core and they can be selectively functionalized. Surprisingly, the position in which halogen is attached has a marked effect in the photophysical properties and modulates the fluorescence capacity of the resulting BODIPY. These iodinated BODIPYs are efficient singlet oxygen generators.