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Synthesis and functionalization of new polyhalogenated BODIPY dyes. Study of their photophysical properties and singlet oxygen generation

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dc.contributor.authorOrtiz García, María Josefa
dc.contributor.authorRodríguez Agarrabeitia, Antonia
dc.contributor.authorDurán Sampedro, Gonzalo
dc.contributor.authorBañuelos Prieto, Jorge
dc.contributor.authorArbeloa Lopez, Teresa
dc.contributor.authorMassad, Walter
dc.contributor.authorMontejano, Hernán
dc.contributor.authorGarcía, Norman
dc.contributor.authorLopez Arbeloa, Iñigo
dc.date.accessioned2024-02-01T14:00:39Z
dc.date.available2024-02-01T14:00:39Z
dc.date.issued2012
dc.description.abstractA theoretical and experimental study on the iodination of BODIPY dyes with different degrees of substitution has been developed. Polyhalogenated BODIPYs synthesized in this work are the first examples of this type of dyes with more than two halogen atoms in the BODIPY core and they can be selectively functionalized. Surprisingly, the position in which halogen is attached has a marked effect in the photophysical properties and modulates the fluorescence capacity of the resulting BODIPY. These iodinated BODIPYs are efficient singlet oxygen generators.en
dc.description.departmentDepto. de Química Orgánica
dc.description.facultyFac. de Ciencias Químicas
dc.description.refereedTRUE
dc.description.sponsorshipMinisterio de Economía, Comercio y Empresa (España)
dc.description.sponsorshipUniversidad Complutense de Madrid
dc.description.sponsorshipEusko Jaurlaritza
dc.description.statuspub
dc.identifier.citationOrtiz García, M. J., Rodríguez Agarrabeitia, A., Durán Sampedro, G. et al. «Synthesis and Functionalization of New Polyhalogenated BODIPY Dyes. Study of Their Photophysical Properties and Singlet Oxygen Generation». Tetrahedron, vol. 68, n.o 4, enero de 2012, pp. 1153-62. https://doi.org/10.1016/j.tet.2011.11.070.
dc.identifier.doi10.1016/j.tet.2011.11.070
dc.identifier.issn0040-4020
dc.identifier.officialurlhttps//doi.org/10.1016/j.tet.2011.11.070
dc.identifier.relatedurlhttps://www.sciencedirect.com/science/article/pii/S0040402011018254
dc.identifier.urihttps://hdl.handle.net/20.500.14352/97790
dc.issue.number4
dc.journal.titleTetrahedron
dc.language.isoeng
dc.page.final1162
dc.page.initial1153
dc.publisherElsevier Ltd.
dc.relation.projectIDinfo:eu-repo/grantAgreement/MEC//MAT2007-65778-C02-02/ES/MODELIZACION MOLECULAR, ESTUDIO ESPECTROSCOPICO Y FOTOFISICA DE COLORANTES LASER EN LA REGION AZUL Y ROJA Y EN DIVERSOS MEDIOS/
dc.relation.projectIDinfo:eu-repo/grantAgreement/MICINN//MAT2010-20646-C04-02/ES/DISEÑO, SINTESIS Y CARACTERIZACION DE NUEVOS COLORANTES ORGANICOS CON EMISION EN LA REGION ESPECTRAL DEL AZUL, ROJO E IR CERCANO, PARA APLICACIONES AVANZADAS/
dc.relation.projectIDGR35/10-A
dc.relation.projectIDS-PE09UN61
dc.rights.accessRightsrestricted access
dc.subject.cdu547
dc.subject.keywordFunctionalization polyhalogenated
dc.subject.keywordBODIPY dye
dc.subject.keywordPhotophy property
dc.subject.keywordSinglet oxygen generator
dc.subject.ucmQuímica orgánica (Química)
dc.subject.unesco23 Química
dc.titleSynthesis and functionalization of new polyhalogenated BODIPY dyes. Study of their photophysical properties and singlet oxygen generationen
dc.typejournal article
dc.type.hasVersionVoR
dc.volume.number68
dspace.entity.typePublication
relation.isAuthorOfPublication07f337af-8a30-4929-81db-4e92176e5c87
relation.isAuthorOfPublication0486160c-3df6-4270-bf91-3e96cd33d85d
relation.isAuthorOfPublication24ec8912-4d0c-471c-9c44-49d62a79827a
relation.isAuthorOfPublication.latestForDiscovery07f337af-8a30-4929-81db-4e92176e5c87

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