Squeezing electrons out of 6s2 lone-pairs in perovskite-type oxides
Loading...
Official URL
Full text at PDC
Publication date
2019
Advisors (or tutors)
Editors
Journal Title
Journal ISSN
Volume Title
Publisher
Royal Society of Chemistry
Citations
Exportar
Citation
Wang, Chun-Hai, et al. «Squeezing Electrons out of 6s 2 Lone-Pairs in Perovskite-Type Oxides». Chemical Communications, vol. 55, n.o 27, 2019, pp. 3887-90. https://doi.org/10.1039/C8CC09608B.
Abstract
Having identified a set of conditions that predispose a solid-state ionic compound to a pressure-induced valence transition, we investigated a series of Bi(III) perovskite oxides. We found such a transition below 10 GPa in every case, including one that we synthesised for the first time (double perovskite-type Ba2BiOsO6).