Palladium-catalyzed cocyclotrimerization of arynes with a pyramidalized alkene

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dc.contributor.authorAlonso Gómez, José Miguel
dc.contributor.authorQuiroga, Sabela
dc.contributor.authorCodony, Sandra
dc.contributor.authorTurcu, Andreea
dc.contributor.authorBarniol-Xicota, Marta
dc.contributor.authorPérez, Dolores
dc.contributor.authorGuitián, Enrique
dc.contributor.authorVázquez, Santiago
dc.contributor.authorPeña, Diego
dc.date.accessioned2024-01-11T14:51:24Z
dc.date.available2024-01-11T14:51:24Z
dc.date.issued2018
dc.description.abstractA pyramidalized alkene and diverse arynes are generated in the presence of a Pd-catalyst to afford [2+2+2] cocycloaddition products. The metal-catalyzed 2+2+2] cocycloaddition of arynes with pyramidalized alkenes is presented. The generation of a highly reactive pyramidalized alkene in the presence of a large excess of in situ-produced arynes led to the corresponding cocyclotrimerization (1 : 2)-adducts in good yields, establishing the first example of a palladium-based reaction of a pyramidalized alkene.
dc.description.departmentDepto. de Química Orgánica
dc.description.facultyFac. de Ciencias Químicas
dc.description.refereedTRUE
dc.description.sponsorshipXunta de Galicia
dc.description.sponsorshipEuropean Commission
dc.description.sponsorshipMinisterio de Ciencia e Innovación (España)
dc.description.statuspub
dc.identifier.citationAlonso, J. M.; Quiroga, S.; Codony, S.; Turcu, A. L.; Barniol-Xicota, M.; Pérez, D.; Guitián, E.; Vázquez, S.; Peña, D. Palladium-catalyzed cocyclotrimerization of arynes with a pyramidalized alkene. Chem. Commun. 2018, 54, 5996-5999 DOI:10.1039/C8CC03188F.
dc.identifier.doi10.1039/c8cc03188f
dc.identifier.essn1364-548X
dc.identifier.issn1359-7345
dc.identifier.officialurlhttps://doi.org/10.1039/C8CC03188F
dc.identifier.urihttps://hdl.handle.net/20.500.14352/92578
dc.issue.number47
dc.journal.titleChemical Communications
dc.language.isoeng
dc.page.final5999
dc.page.initial5996
dc.publisherRoyal Society of Chemistry
dc.rights.accessRightsrestricted access
dc.subject.cdu547
dc.subject.ucmCiencias
dc.subject.unesco23 Química
dc.titlePalladium-catalyzed cocyclotrimerization of arynes with a pyramidalized alkene
dc.typejournal article
dc.type.hasVersionVoR
dc.volume.number54
dspace.entity.typePublication
relation.isAuthorOfPublicationd770fa51-b1e8-4963-9d05-4c3f2fcc4380
relation.isAuthorOfPublication.latestForDiscoveryd770fa51-b1e8-4963-9d05-4c3f2fcc4380
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