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(Ph3P)AuCl-catalyzed homocoupling of arylboronic acids under benchtop conditions: Synthesis of biphenyls

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dc.contributor.authorRoscales García, Silvia
dc.contributor.authorSánchez-Sancho, Francisco
dc.contributor.authorGarcía Csaky, Aurelio
dc.date.accessioned2024-06-20T10:38:00Z
dc.date.available2024-06-20T10:38:00Z
dc.date.issued2023
dc.description.abstract(Ph3P)AuCl was discovered to be a powerful catalyst in the homocoupling of arylboronic acids and potassium aryltrifluoroborates for the synthesis of symmetrical biaryls. The reactions take place under benchtop reaction conditions in 96% EtOH at temperatures between rt and 50 °C with no exclusion of air or humidity, in the presence of F-TEDA (Selectfluor™) as an oxidant. The procedure is very functional group tolerant, and affords the corresponding biaryls in high yields with large substrate scope (26 examples).
dc.description.departmentDepto. de Química Orgánica
dc.description.facultyInstituto Pluridisciplinar (IP)
dc.description.fundingtypeAPC financiada por la UCM
dc.description.refereedTRUE
dc.description.sponsorshipMinisterio de Ciencia y Educación
dc.description.statuspub
dc.identifier.citationSilvia Roscales, Francisco Sánchez-Sancho, Aurelio G. Csáky, (Ph3P)AuCl-catalyzed homocoupling of arylboronic acids under benchtop conditions: Synthesis of biphenyls, Molecular Catalysis, Volume 547, 2023, 113281, ISSN 2468-8231, https://doi.org/10.1016/j.mcat.2023.113281. (https://www.sciencedirect.com/science/article/pii/S2468823123003656)
dc.identifier.doi10.1016/j.mcat.2023.113281
dc.identifier.issn2468-8231
dc.identifier.officialurlhttps://doi.org/10.1016/j.mcat.2023.113281
dc.identifier.relatedurlhttps://www.sciencedirect.com/science/article/pii/S2468823123003656
dc.identifier.urihttps://hdl.handle.net/20.500.14352/105128
dc.journal.titleMolecular Catalysis
dc.language.isoeng
dc.publisherElsevier
dc.relation.projectIDPID2021–124419NB-I00
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 Internationalen
dc.rights.accessRightsopen access
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/
dc.subject.cdu544.2
dc.subject.keywordGold
dc.subject.keywordBoronic acids
dc.subject.keywordHomocoupling
dc.subject.keywordBiphenyls
dc.subject.ucmQuímica física (Química)
dc.subject.unesco2307 Química Física
dc.title(Ph3P)AuCl-catalyzed homocoupling of arylboronic acids under benchtop conditions: Synthesis of biphenyls
dc.typejournal article
dc.type.hasVersionVoR
dc.volume.number547
dspace.entity.typePublication
relation.isAuthorOfPublicationef4f93d7-a007-4514-9055-f8ba8c41138d
relation.isAuthorOfPublication20fb9911-4424-43a0-ad98-890ff7a6dacd
relation.isAuthorOfPublication.latestForDiscoveryef4f93d7-a007-4514-9055-f8ba8c41138d

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