Palladium‐catalyzed hydroarylation of homopropargyl iodoindoles with concurrent alkyl and iodonium migrations
| dc.contributor.author | Martín, Irene | |
| dc.contributor.author | Aragoncillo Abanades, Cristina | |
| dc.contributor.author | Almendros Requena, Pedro | |
| dc.date.accessioned | 2024-01-09T09:16:50Z | |
| dc.date.available | 2024-01-09T09:16:50Z | |
| dc.date.issued | 2021 | |
| dc.description.abstract | A selective palladium‐catalyzed C-arylation/carbocyclization/iodonium migration reaction sequence has been accomplished. Novel 2‐iodo‐1‐aryl‐9-H‐carbazoles are now easily available. As this result is contrary to the selectivity observed using gold catalysis, the formation of 2‐iodocarbazoles is noticeable, suggesting a metal‐controlled cyclization through chemo‐ and regioselective 1,2‐alkyl migration and 1,4‐iodonium migration. | |
| dc.description.department | Depto. de Química Orgánica | |
| dc.description.faculty | Fac. de Ciencias Químicas | |
| dc.description.refereed | TRUE | |
| dc.description.sponsorship | Ministerio de Ciencia e Innovación (España) | |
| dc.description.sponsorship | European Commission | |
| dc.description.status | pub | |
| dc.identifier.citation | Martín-Mejías I, Aragoncillo C, Almendros P. Palladium-Catalyzed Hydroarylation of Homopropargyl Iodoindoles with Concurrent Alkyl and Iodonium Migrations. Adv. Synth. Catal. 2021, 363, 1449-1456. | |
| dc.identifier.doi | 10.1002/adsc.202001267 | |
| dc.identifier.essn | 1615-4169 | |
| dc.identifier.issn | 1615-4150 | |
| dc.identifier.officialurl | https://doi.org/10.1002/adsc.202001267 | |
| dc.identifier.uri | https://hdl.handle.net/20.500.14352/91934 | |
| dc.issue.number | 5 | |
| dc.journal.title | Advance Synthesis & Catalysis | |
| dc.language.iso | eng | |
| dc.page.final | 1456 | |
| dc.page.initial | 1449 | |
| dc.publisher | Wiley-WCH GmbH | |
| dc.relation.projectID | (Project PGC2018-095025-B-100) | |
| dc.rights.accessRights | restricted access | |
| dc.subject.cdu | 547 | |
| dc.subject.keyword | Carbazole | |
| dc.subject.keyword | Cyclization | |
| dc.subject.keyword | Homogeneous catalysis | |
| dc.subject.keyword | Iodonium migration | |
| dc.subject.keyword | Palladium | |
| dc.subject.ucm | Ciencias | |
| dc.subject.unesco | 2306 Química Orgánica | |
| dc.subject.unesco | 2306.10 Compuestos Heterocíclicos | |
| dc.title | Palladium‐catalyzed hydroarylation of homopropargyl iodoindoles with concurrent alkyl and iodonium migrations | |
| dc.type | journal article | |
| dc.type.hasVersion | VoR | |
| dc.volume.number | 363 | |
| dspace.entity.type | Publication | |
| relation.isAuthorOfPublication | 8b257537-0758-463d-9e75-ac1e3d55f9a6 | |
| relation.isAuthorOfPublication | ee8363b4-4019-453d-abd3-6258ecc4299f | |
| relation.isAuthorOfPublication.latestForDiscovery | 8b257537-0758-463d-9e75-ac1e3d55f9a6 |